Structures of bromoalkanes' photodissociation in solution by means of ultrafast extended x-ray absorption fine-structure spectroscopy.

Oulianov, D A; Tomov, I V; Dvornikov, A S; Rentzepis, P M · Proc Natl Acad Sci U S A · 2002

basic_science · Level V

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Abstract

The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 A by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is also discussed.

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