Direct atom-resolved imaging of oxides and their grain boundaries.

Zhang, Zaoli; Sigle, Wilfried; Phillipp, Fritz; Rühle, Manfred · Science · 2003

basic_science · Level V

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Abstract

Using high-resolution transmission electron microscopy, we obtained structure images of strontium titanate (SrTiO3) with a clearly resolved oxygen sublattice along different crystallographic directions in the bulklattice and for a Sigma3 tilt grain boundary. Comparison with image simulations showed that the grain boundary contains oxygen vacancies. Measurements of atom displacements near the grain boundary revealed close correspondence with theoretical calculations.