Contiguous stereogenic quaternary carbons: a daunting challenge in natural products synthesis.
review · Level V
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- Record sourced from PubMed, PMID 15232003.
- Also identified by PMC identifier 514413.
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Abstract
One element of structure that invariably increases the difficulty of a chemical synthesis is the presence in the target molecule of contiguous all-carbon quaternary stereocenters. This Perspective will examine the most useful transformations and strategies devised recently for directly assembling this structural unit.
Medical subject headings
- Biological Products