Enhancement of ferroelectricity in strained BaTiO3 thin films.

Choi, K J; Biegalski, M; Li, Y L; Sharan, A; Schubert, J; Uecker, R; Reiche, P; Chen, Y B et al. · Science · 2004

basic_science · Level V

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Abstract

Biaxial compressive strain has been used to markedly enhance the ferroelectric properties of BaTiO3 thin films. This strain, imposed by coherent epitaxy, can result in a ferroelectric transition temperature nearly 500 degrees C higher and a remanent polarization at least 250% higher than bulk BaTiO3 single crystals. This work demonstrates a route to a lead-free ferroelectric for nonvolatile memories and electro-optic devices.