Defined DNA/nanoparticle conjugates.

Ackerson, Christopher J; Sykes, Michael T; Kornberg, Roger D · Proc Natl Acad Sci U S A · 2005

basic_science · Level V

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Abstract

Glutathione monolayer-protected gold clusters were reacted by place exchange with 19- or 20-residue thiolated oligonucleotides. The resulting DNA/nanoparticle conjugates could be separated on the basis of the number of bound oligonucleotides by gel electrophoresis and assembled with one another by DNA-DNA hybridization. This approach overcomes previous limitations of DNA/nanoparticle synthesis and yields conjugates that are precisely defined with respect to both gold and nucleic acid content.

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