Losing the expression of molecular chirality in self-assembled physisorbed monolayers.
basic_science · Level V
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Abstract
STM imaging on graphite of the S-enantiomer of a chiral diacetylene isophthalic acid derivative reveals that molecular chirality is not expressed in the monolayer due to a specific molecular conformation preventing the stereogenic center to transfer its chiral information.
Medical subject headings
- Acetylene
- Crystallization
- Graphite
- Membranes, Artificial
- Nanostructures
- Phthalic Acids