Electric field tuning of plasmonic response of nanodot array in liquid crystal matrix.

Kossyrev, Pavel A; Yin, Aijun; Cloutier, Sylvain G; Cardimona, David A; Huang, Danhong; Alsing, Paul M; Xu, Jimmy M · Nano Lett · 2005

basic_science · Level V

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Abstract

In this work we demonstrate the feasibility of electric-field tuning of the plasmonic spectrum of a novel gold nanodot array in a liquid crystal matrix. As opposed to previously reported microscopically observed near-field spectral tuning of individual gold nanoparticles, this system exhibits macroscopic far-field spectral tuning. The nanodot-liquid crystal matrix also displays strong anisotropic absorption characteristics, which can be effectively described as a collective ensemble within a composite matrix in the lateral dimension and a group of noninteracting individual particles in the normal direction. The effective medium model and the Mie theory are employed to describe the experimental results.