Symmetry considerations in CdSe nanocrystals.

Dalpian, Gustavo M; Tiago, Murilo L; Lopez del Puerto, Marie; Chelikowsky, James R · Nano Lett · 2006

basic_science · Level V

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Abstract

Semiconductor nanocrystals or quantum dots show a wide range of physical properties depending on their size or shape. In this paper, we show that symmetry is also an important characteristic that can lead to different electronic and optical properties. We use pseudopotential density-functional theory, within a real space approach, and address the sensitivity of electronic and optical properties with respect to the symmetry point groups associated to CdSe nanocrystals.