Surface water and the origin of the positive excess specific heat for 7 nm rutile and anatase nanoparticles.

Boerio-Goates, Juliana; Li, Guangshe; Li, Liping; Walker, Trent F; Parry, Thomas; Woodfield, Brian F · Nano Lett · 2006

other · Level V

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Abstract

Specific heats (15-350 K) have been measured on 7 nm TiO2 anatase and rutile nanoparticles containing significant amounts of surface-adsorbed water. By successively reducing the water content without changing particle size, we observed two types of water behavior. The specific heat of bare 7 nm particles was estimated using the water specific heats. Contrary to previous literature reports, the bare small particle specific heats are the same as those of the bulk, within experimental error.

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