Time-resolved investigation of bright visible wavelength luminescence from sulfur-doped ZnO nanowires and micropowders.

Foreman, John V; Li, Jianye; Peng, Hongying; Choi, Soojeong; Everitt, Henry O; Liu, Jie · Nano Lett · 2006

basic_science · Level V

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Abstract

Sulfur-doped zinc oxide (ZnO) nanowires grown on gold-coated silicon substrates inside a horizontal tube furnace exhibit remarkably strong visible wavelength emission with a quantum efficiency of 30%, an integrated intensity 1600 times stronger than band edge ultraviolet emission, and a spectral distribution that closely matches the dark-adapted human eye response. By comparatively studying sulfur-doped and undoped ZnO micropowders, we clarify how sulfur doping and nanostructuring affect the visible luminescence and the underlying energy transfer mechanisms.

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