Field-enhanced photocurrent spectroscopy of excitonic states in single-wall carbon nanotubes.

Mohite, Aditya; Lin, Ji-Tzuoh; Sumanasekera, Gamini; Alphenaar, Bruce W · Nano Lett · 2006

basic_science · Level V

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Abstract

Excitonic and free-carrier transitions in single-wall carbon nanotubes are distinguished using field-enhanced photocurrent spectroscopy. Electric field dissociation allows for the detection of bound-exciton states that otherwise would not contribute to the photocurrent. Excitonic states associated with both the ground-state semiconductor and the ground-state metallic nanotube transitions are resolved. The observation of a metallic excitonic state corroborates recent predictions of a symmetry gap existing in metallic nanotubes.

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