Self-assembly of laterally-tethered nanorods.

Horsch, Mark A; Zhang, Zhenli; Glotzer, Sharon C · Nano Lett · 2006

basic_science · Level V

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Abstract

We report results from a computational study of laterally tethered nanorod "shape amphiphiles". Our simulations predict that the model nanorods self-assemble into stepped-ribbon-like micelles, a centered rectangular stepped-ribbon phase, and two structurally different liquid crystalline bilayer phases: one in which the bilayers have C(mm) symmetry and another in which they have P(2) symmetry. We provide a possible explanation for the transition between the two C(mm) and P(2) liquid crystalline phases.

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