Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones.
basic_science · Level V
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- Record sourced from PubMed, PMID 17360603.
- Also identified by PMC identifier 1805593.
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Abstract
Cyanosilylation of aldehydes and aliphatic ketones can be carried out in dimethylformamide even without the use of any catalyst. In the presence of nucleophilic catalysts such as carbonate and phosphate salts, the reaction rate is significantly enhanced.
Medical subject headings
- Aldehydes
- Carbonates
- Cyanides
- Dimethylformamide
- Ketones
- Phosphates
- Trimethylsilyl Compounds