Moving nanoparticles with Raman scattering.

Ringler, M; Klar, T A; Schwemer, A; Susha, A S; Stehr, J; Raschke, G; Funk, S; Borowski, M et al. · Nano Lett · 2007

basic_science · Level V

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Abstract

We show how to change optically the distance between two protein-linked gold nanoparticles by Raman-induced motion of the linker protein. Rayleigh scattering spectroscopy of the coupled-particle plasmon allows us to compare the inter-nanoparticle distance of individual protein-linked gold nanoparticle dimers before and after surface-enhanced Raman scattering (SERS). We find that low-intensity (50 microW/microm2) laser light in resonance with the nanoparticle-dimer plasmon provokes a change of the inter-nanoparticle distance on the order of 0.5 nm whenever SERS from the proteins connecting the nanoparticles can be observed.

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