Controlling the lattice parameters of gold nanoparticle FCC crystals with duplex DNA linkers.

Hill, Haley D; Macfarlane, Robert J; Senesi, Andrew J; Lee, Byeongdu; Park, Sung Yong; Mirkin, Chad A · Nano Lett · 2008

basic_science · Level V

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Abstract

DNA-functionalized gold nanoparticles can be used to induce the formation and control the unit cell parameters of highly ordered face-centered cubic crystal lattices. Nanoparticle spacing increases linearly with longer DNA interconnect length, yielding maximum unit cell parameters of 77 nm and 0.52% inorganic-filled space for the DNA constructs studied. In general, we show that longer DNA connections result in a decrease in the overall crystallinity and order of the lattice due to greater conformational flexibility.

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