Schottky solar cells based on colloidal nanocrystal films.

Luther, Joseph M; Law, Matt; Beard, Matthew C; Song, Qing; Reese, Matthew O; Ellingson, Randy J; Nozik, Arthur J · Nano Lett · 2008

basic_science · Level V

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Abstract

We describe here a simple, all-inorganic metal/NC/metal sandwich photovoltaic (PV) cell that produces an exceptionally large short-circuit photocurrent (>21 mA cm(-2)) by way of a Schottky junction at the negative electrode. The PV cell consists of a PbSe NC film, deposited via layer-by-layer (LbL) dip coating that yields an EQE of 55-65% in the visible and up to 25% in the infrared region of the solar spectrum, with a spectrally corrected AM1.5G power conversion efficiency of 2.1%. This NC device produces one of the largest short-circuit currents of any nanostructured solar cell, without the need for sintering, superlattice order or separate phases for electron and hole transport.