Colloidal silicon nanorod synthesis.

Heitsch, Andrew T; Hessel, Colin M; Akhavan, Vahid A; Korgel, Brian A · Nano Lett · 2009

basic_science · Level V

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Abstract

The colloidal synthesis of crystalline silicon (Si) nanorods with diameters of 5 to 10 nm and lengths of 15 to 75 nm is demonstrated. Trisilane was decomposed in a hot solvent in the presence of dodecylamine and gold (Au) nanocrystals. Nanorods form by Au-seeded solution-liquid-solid growth with dodecylamine serving as capping ligands that stabilize the nanorod dispersion. Post-synthesis etching of the Au seeds from the nanorod tips is also demonstrated.