Cathodoluminescence studies of the inhomogeneities in Sn-doped Ga2O3 nanowires.

Maximenko, S I; Mazeina, L; Picard, Y N; Freitas, J A; Bermudez, V M; Prokes, S M · Nano Lett · 2009

basic_science · Level V

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Abstract

Cathodoluminescence real-color imaging and spectroscopy were employed to study the properties of Ga(2)O(3) nanowires grown with different Sn/Ga ratios. The structures grown under Sn-rich conditions show large spectral emission variation, ranging from blue to red, with a green transition zone. Spectral emission changes correlate with changes in the chemical composition and structure found by energy dispersive spectroscopy and electron diffraction. A sharp transition from green to red emission correlates with a phase transition of beta-Ga(2)O(3) to polycrystalline SnO(2). The origin of the green emission band is discussed based on ab initio calculation results.

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