Fanoshells: nanoparticles with built-in Fano resonances.

Mukherjee, Shaunak; Sobhani, Heidar; Lassiter, J Britt; Bardhan, Rizia; Nordlander, Peter; Halas, Naomi J · Nano Lett · 2010

basic_science · Level V

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Abstract

A nanoparticle consisting of a dielectric (SiO(2)) and metallic (Au) shell layer surrounding a solid Au nanoparticle core can be designed with its superradiant and subradiant plasmon modes overlapping in energy, resulting in a Fano resonance in its optical response. Synthesis of this nanoparticle around an asymmetric core yields a structure that possesses additional Fano resonances as revealed by single particle dark field microspectroscopy. A mass-and-spring coupled oscillator model provides an excellent description of the plasmon interactions and resultant optical response of this nanoparticle.