Diffusion-driven crystal structure transformation: synthesis of Heusler alloy Fe3Si nanowires.

Seo, Kwanyong; Bagkar, Nitin; Kim, Si-in; In, Juneho; Yoon, Hana; Jo, Younghun; Kim, Bongsoo · Nano Lett · 2010

basic_science · Level V

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Abstract

We report fabrication of Heusler alloy Fe(3)Si nanowires by a diffusion-driven crystal structure transformation method from paramagnetic FeSi nanowires. Magnetic measurements of the Fe(3)Si nanowire ensemble show high-temperature ferromagnetic properties with T(c) >> 370 K. This methodology is also successfully applied to Co(2)Si nanowires in order to obtain metal-rich nanowires (Co) as another evidence of the structural transformation process. Our newly developed nanowire crystal transformation method would be valuable as a general method to fabricate metal-rich silicide nanowires that are otherwise difficult to synthesize.