Large scale growth and characterization of atomic hexagonal boron nitride layers.

Song, Li; Ci, Lijie; Lu, Hao; Sorokin, Pavel B; Jin, Chuanhong; Ni, Jie; Kvashnin, Alexander G; Kvashnin, Dmitry G et al. · Nano Lett · 2010

basic_science · Level V

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Abstract

Hexagonal boron nitride (h-BN), a layered material similar to graphite, is a promising dielectric. Monolayer h-BN, so-called "white graphene", has been isolated from bulk BN and could be useful as a complementary two-dimensional dielectric substrate for graphene electronics. Here we report the large area synthesis of h-BN films consisting of two to five atomic layers, using chemical vapor deposition. These atomic films show a large optical energy band gap of 5.5 eV and are highly transparent over a broad wavelength range. The mechanical properties of the h-BN films, measured by nanoindentation, show 2D elastic modulus in the range of 200-500 N/m, which is corroborated by corresponding theoretical calculations.