Fabrication of highly conductive and transparent thin films from single-walled carbon nanotubes using a new non-ionic surfactant via spin coating.
basic_science · Level V
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- Record sourced from PubMed, PMID 20735061.
- Also identified by DOI 10.1021/nn1009837.
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Abstract
Oligothiophene-terminated poly(ethylene glycol) was synthesized and used as a non-ionic and amphiphilic surfactant for fabricating high-quality single-walled carbon nanotube (SWCNT) films by a simple spin coating method. The absence of charge repulsion between SWCNT/surfactant complexes successfully leads to formation of a dense network of SWCNTs on the substrate through a single deposition of spin coating. When the SWCNT film was treated with nitric acid and thionyl chloride after washed with dichloromethane and water, a high-performance SWCNT film with the sheet resistance of 59 ohm/sq and the transparency of 71% at 550 nm was successfully obtained. Since the SWCNT film exhibits a high value of σ(dc)/σ(ac) (∼17) and excellent dimensional stability after releasing from the substrate, the film can be used as a transparent electrode in flexible optoelectronic devices.