Probing exciton localization in single-walled carbon nanotubes using high-resolution near-field microscopy.

Georgi, Carsten; Green, Alexander A; Hersam, Mark C; Hartschuh, Achim · ACS Nano · 2010

basic_science · Level V

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Abstract

We observe localization of excitons in semiconducting single-walled carbon nanotubes at room temperature using high-resolution near-field photoluminescence (PL) microscopy. Localization is the result of spatially confined exciton energy minima with depths of more than 15 meV connected to lateral energy gradients exceeding 2 meV/nm as evidenced by energy-resolved PL imaging. Simulations of exciton diffusion in the presence of energy variations support this interpretation predicting strongly enhanced PL at local energy minima.

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