Hybrid, elastomeric hydrogels crosslinked by multifunctional block copolymer micelles.

Xiao, Longxi; Liu, Chao; Zhu, Jiahua; Pochan, Darrin J; Jia, Xinqiao · Soft Matter · 2010

basic_science · Level V

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Abstract

Amphiphlic block copolymers consisting of hydrophilic, poly(acrylic acid) randomly decorated with acrylate groups and hydrophobic, rubbery poly(n-butyl acrylate) self-assembled into well-defined micelles with an average diameter of ~21 nm. Radical polymerization of acrylamide in the presence of the crosslinkable micelles gave rise to hybrid, elastomeric hydrogels whose mechancial properties can be readily tuned by varying the BCM concentration.