Plasmonic nanohybrid with ultrasmall Ag nanoparticles and fluorescent dyes.

Rainò, Gabriele; Stöferle, Thilo; Park, Chanhee; Kim, Ho-Cheol; Topuria, Teya; Rice, Philip M; Chin, In-Joo; Miller, Robert D et al. · ACS Nano · 2011

basic_science · Level V

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Abstract

We investigate a hybrid nanocomposite combining fluorescent dyes and ultrasmall (<3 nm) silver nanocrystals in a block copolymer micelle. Although the metal nanoparticles are significantly smaller than the electromagnetic skin depth, we observe a modification of the exciton lifetime and the nonradiative energy transfer among the dyes. This behavior is absent in a control experiment with dyes whose energetic levels are far from the plasmonic resonance, establishing the plasmonic nature of the interaction.

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