Synthesis and electrochemical properties of spin-capable carbon nanotube sheet/MnO(x) composites for high-performance energy storage devices.
basic_science · Level V
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- Record sourced from PubMed, PMID 21661756.
- Also identified by DOI 10.1021/nl200513a.
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Abstract
Inspired by the high specific capacitances found using ultrathin films or nanoparticles of manganese oxides (MnO(x)), we have electrodeposited MnO(x) nanoparticles onto sheets of carbon nanotubes (CNT sheets). The resulting composites have high specific capacitances (C(sp) ≤ 1250 F/g), high charge/discharge rate capabilities, and excellent cyclic stability. Both the C(sp) and rate capabilities are controlled by the average size of the MnO(x) nanoparticles on the CNTs. They are independent of the number of layers of CNT sheets used to form an electrode. The high-performance composites result from a synergistic combination of large surface area and good electron-transport capabilities of the MnO(x) nanoparticles with the good conductivity of the CNT sheets. Such composites can be used as electrodes for lithium batteries and supercapacitors.
Medical subject headings
- Electric Power Supplies
- Manganese Compounds
- Nanocomposites
- Nanotubes, Carbon
- Oxides