Stereoselective synthesis, efficient light emission, and high bipolar charge mobility of chiasmatic luminogens.

Zhao, Zujin; Lam, Jacky W Y; Chan, Carrie Y K; Chen, Shuming; Liu, Jianzhao; Lu, Ping; Rodriguez, Mario; Maldonado, José-Luis et al. · Adv Mater · 2011

basic_science · Level V

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Abstract

Stereoregular tetraphenylethene derivatives (Z)-o-BCaPTPE and (Z)-o-BTPATPE featured with chiasmatic conformations and aggregation-enhanced emission characteristics are synthesized using a McMurry reaction. Both luminogens exhibit high hole and electron mobilities. Organic light-emitting diodes (OLEDs) using (Z)-o-BCaPTPE and (Z)-o-BTPATPE as both the light-emitting and electron-transporting layers show high efficiencies.

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