Linear self-assembly of nanoparticles within liquid crystal defect arrays.

Coursault, Delphine; Grand, Johan; Zappone, Bruno; Ayeb, Habib; Lévi, Georges; Félidj, Nordin; Lacaze, Emmanuelle · Adv Mater · 2012

basic_science · Level V

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Abstract

In the presence of oriented smectic liquid crystal defects, hybrid systems of nanoparticles/liquid crystals form straight chains of nanoparticles of length longer than tens of micrometers and width equal to one single nanoparticle. The interparticle distance in a chain can be varied between a few micrometers and 1.5 nm, highlighting the control of optical absorption by light polarization monitored by gold nanoparticle concentration.

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