Continuous electrical tuning of the chemical composition of TaO(x)-based memristors.

Miao, Feng; Yi, Wei; Goldfarb, Ilan; Yang, J Joshua; Zhang, Min-Xian; Pickett, Matthew D; Strachan, John Paul; Medeiros-Ribeiro, Gilberto et al. · ACS Nano · 2012

basic_science · Level V

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Abstract

TaO(x)-based memristors have recently demonstrated both subnanosecond resistance switching speeds and very high write/erase switching endurance. Here we show that the physical state variable that enables these properties is the oxygen concentration in a conduction channel, based on the measurement of the thermal coefficient of resistance of different TaO(x) memristor states and a set of reference Ta-O films of known composition. The continuous electrical tunability of the oxygen concentration in the channel, with a resolution of a few percent, was demonstrated by controlling the write currents with a one transistor-one memristor (1T1M) circuit. This study demonstrates that solid-state chemical kinetics is important for the determination of the electrical characteristics of this relatively new class of device.