Aligned growth of gold nanorods in PMMA channels: parallel preparation of nanogaps.

Jain, Titoo; Lara-Avila, Samuel; Kervennic, Yann-Vai; Moth-Poulsen, Kasper; Nørgaard, Kasper; Kubatkin, Sergey; Bjørnholm, Thomas · ACS Nano · 2012

basic_science · Level V

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Abstract

We demonstrate alignment and positional control of gold nanorods grown in situ on substrates using a seed-mediated synthetic approach. Alignment control is obtained by directing the growth of spherical nanoparticle seeds into nanorods in well-defined poly(methyl methacrylate) nanochannels. Substrates with prepatterned metallic electrodes provide an additional handle for the position of the gold nanorods and yield nanometer-sized gaps between the electrode and nanorod. The presented approach is a novel demonstration of bottom-up device fabrication of multiple nanogap junctions on a single chip mediated viain situ growth of gold nanorods acting as nanoelectrodes.