Scanning tunneling microscopy study and nanomanipulation of graphene-coated water on mica.

He, Kevin T; Wood, Joshua D; Doidge, Gregory P; Pop, Eric; Lyding, Joseph W · Nano Lett · 2012

basic_science · Level V

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Abstract

We study interfacial water trapped between a sheet of graphene and a muscovite (mica) surface using Raman spectroscopy and ultrahigh vacuum scanning tunneling microscopy (UHV-STM) at room temperature. We are able to image the graphene-water interface with atomic resolution, revealing a layered network of water trapped underneath the graphene. We identify water layer numbers with a carbon nanotube height reference. Under normal scanning conditions, the water structures remain stable. However, at greater electron energies, we are able to locally manipulate the water using the STM tip.

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