Strong phonon scattering by layer structured PbSnS(2) in PbTe based thermoelectric materials.

He, Jiaqing; Girard, Steven N; Zheng, Jin-Cheng; Zhao, Lidong; Kanatzidis, Mercouri G; Dravid, Vinayak P · Adv Mater · 2012

basic_science · Level V

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Abstract

The incorporation of PbSnS(2) in PbTe results in a tremendous reduction of the lattice thermal conductivity to 0.8 W/mK at room temperature, a reduction of almost 60% over bulk PbTe. Transmission electron microscopy reveals very high density displacement layers, misfit dislocations, and phase boundaries. Our thermal transport calculations based on modified Debye-Callaway model, well in agreement with the experimental measurements, reveal that the layer structured PbSnS(2) plays an important role in reducing the lattice thermal conductivity.

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