One-pot radical polymerization of one inimer to form one-dimensional polymeric nanomaterials.

Ma, Pengju; Nie, Hui; Zhou, Qingqing; Li, Yuesheng; Liu, Hewen · Adv Mater · 2012

basic_science · Level V

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Abstract

A one-pot polymerization strategy is put forward for producing 1D polymeric nanomaterials directly from a single inimer. An inimer bearing an NMP initiating site is polymerized in the presence of a RAFT CTA to form a pearl-necklace structure constituted of hyperbranched polymer "pearls". The obtained 1D nanorods show high regularity evidenced by the long-range order in small angle XRD patterns and the formation of liquid crystalline phases.

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