Influence of alkyl chain branching positions on the hole mobilities of polymer thin-film transistors.

Lei, Ting; Dou, Jin-Hu; Pei, Jian · Adv Mater · 2012

basic_science · Level V

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Abstract

Four polymers that contain alkyl chains branched at different positions on the polymer backbone are prepared. A polymer with 4-decyltetradecyl chains gives an impressive mobility of 3.62 cm(2) V(-1) s(-1) . This may arise from tighter polymer packing as well as stacking conformation change of the polymer backbone induced by the branching of the alkyl chains.

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