Hypercrosslinked aromatic heterocyclic microporous polymers: a new class of highly selective CO2 capturing materials.

Luo, Yali; Li, Buyi; Wang, Wei; Wu, Kangbing; Tan, Bien · Adv Mater · 2012

basic_science · Level V

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Abstract

Aromatic heterocyclic microporous polymers with high surface areas are obtained by directly crosslinking of the heterocyclic monomers under mild conditions. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit high CO(2) adsorption capacity and selectivity. At 273 K, the CO(2)/N(2) selectivity of Py-1 is about 117, which is among the highest the reported microporous materials.

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