Solvent-induced delamination of a multifunctional two dimensional coordination polymer.

Gallego, Almudena; Hermosa, Cristina; Castillo, Oscar; Berlanga, Isadora; Gómez-García, Carlos J; Mateo-Martí, Eva; Martínez, José I; Flores, Fernando et al. · Adv Mater · 2013

basic_science · Level V

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Abstract

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.