High-index facets in gold nanocrystals elucidated by coherent electron diffraction.

Shah, Amish B; Sivapalan, Sean T; DeVetter, Brent M; Yang, Timothy K; Wen, Jianguo; Bhargava, Rohit; Murphy, Catherine J; Zuo, Jian-Min · Nano Lett · 2013

basic_science · Level V

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Abstract

Characterization of high-index facets in noble metal nanocrystals for plasmonics and catalysis has been a challenge due to their small sizes and complex shapes. Here, we present an approach to determine the high-index facets of nanocrystals using streaked Bragg reflections in coherent electron diffraction patterns, and provide a comparison of high-index facets on unusual nanostructures such as trisoctahedra. We report new high-index facets in trisoctahedra and previous unappreciated diversity in facet sharpness.

Medical subject headings