"Raisin bun"-like nanocomposites of palladium clusters and porphyrin for superior formic acid oxidation.

Wang, Xiuxin; Yang, Jiandong; Yin, Huajie; Song, Rui; Tang, Zhiyong · Adv Mater · 2013

basic_science · Level V

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Abstract

A novel "raisin bun"-like nanocomposite, where Pd clusters are embedded in porphyrin matrix, is developed as a promising electrocatalyst. Thanks to the synergy between the Pd clusters and the porphyrin matrix, this composite exhibits a low oxidation potential, high mass activity and excellent stability toward electrochemical oxidation of formic acid, which opens new routes for the design of high-performance catalysts in fuel cells.

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