A molecular thermometer for nanoparticles for optical hyperthermia.

Freddi, Stefano; Sironi, Laura; D'Antuono, Rocco; Morone, Diego; Donà, Alice; Cabrini, Elisa; D'Alfonso, Laura; Collini, Maddalena et al. · Nano Lett · 2013

basic_science · Level V

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Abstract

We developed an all-optical method to measure the temperature on gold (nanorods and nanostars) and magnetite nanoparticles under near-infrared and radiofrequency excitation by monitoring the excited state lifetime of Rhodamine B that lies within =/~20 nm from the nanoparticle surface. We reached high temperature sensitivity (0.029 ± 0.001 ns/°C) and low uncertainty (±0.3 °C). Gold nanostars are =/~3 and =/~100 times more efficient than gold nanorods and magnetite nanoparticles in inducing localized hyperthermia.

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