Iron sulfide (FeS) nanotubes using sulfurization of hematite nanowires.

Cummins, Dustin R; Russell, Harry B; Jasinski, Jacek B; Menon, Madhu; Sunkara, Mahendra K · Nano Lett · 2013

basic_science · Level V

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Abstract

We report the phase transformation of hematite (α-Fe2O3) single crystal nanowires to crystalline FeS nanotubes using sulfurization with H2S gas at relatively low temperatures. Characterization indicates that phase pure hexagonal FeS nanotubes were formed. Time-series sulfurization experiments suggest epitaxial growth of FeS as a shell layer on hematite. This is the first report of hollow, crystalline FeS nanotubes with NiAs structure and also on the Kirkendall effect in solid-gas reactions with nanowires involving sulfurization.