Change of the magnetic coupling of a metal-organic complex with the substrate by a stepwise ligand reaction.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 23985020.
- Also identified by DOI 10.1021/nl402575c.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
The surface-assisted intramolecular ligand reaction of a porphyrin molecule adsorbed on Au(111) is studied by scanning tunneling microscopy and spectroscopy. The temperature-induced stepwise transformation of iron octaethylporphyrin proceeds via a concentric electrocyclic ring closure, with the final product iron tetrabenzoporphyrin being identified by its characteristic Kondo resonance. Along with the transformation of the organic ligand, changes in the magnetic fingerprint are observed, indicating an increasing coupling of the iron spin with the substrate electrons.
Medical subject headings
- Coordination Complexes
- Iron
- Porphyrins