Interface-engineered bistable [2]rotaxane-graphene hybrids with logic capabilities.

Jia, Chuancheng; Li, Hao; Jiang, Jiaolong; Wang, Jindong; Chen, Hongliang; Cao, Dennis; Stoddart, J Fraser; Guo, Xuefeng · Adv Mater · 2013

basic_science · Level V

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Abstract

The use of high-quality graphene as a local probe in combination with photo excitation helps to establish a deep mechanistic understanding of charge generation/quenching processes under lying the graphene/environment interface. By combining a non-destructive bottom-up assembly technique with sensitive graphene-based transistors, a bistable [2]rotaxane-graphene hybrid device, which exhibits a symmetric mirror-image photoswitching effect with logic capabilities, is produced.