A plasma-treated chalcogenide switch device for stackable scalable 3D nanoscale memory.

Lee, Myoung-Jae; Lee, Dongsoo; Cho, Seong-Ho; Hur, Ji-Hyun; Lee, Sang-Moon; Seo, David H; Kim, Dong-Sik; Yang, Moon-Seung et al. · Nat Commun · 2013

basic_science · Level V

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Abstract

Stackable select devices such as the oxide p-n junction diode and the Schottky diode (one-way switch) have been proposed for non-volatile unipolar resistive switching devices; however, bidirectional select devices (or two-way switch) need to be developed for bipolar resistive switching devices. Here we report on a fully stackable switching device that solves several problems including current density, temperature stability, cycling endurance and cycle distribution. We demonstrate that the threshold switching device based on As-Ge-Te-Si material significantly improves cycling endurance performance by reactive nitrogen deposition and nitrogen plasma hardening. Formation of the thin Si₃N₄ glass layer by the plasma treatment retards tellurium diffusion during cycling. Scalability of threshold switching devices is measured down to 30 nm scale with extremely fast switching speed of ~2 ns.