Synergistic effect of fluorination on molecular energy level modulation in highly efficient photovoltaic polymers.

Zhang, Maojie; Guo, Xia; Zhang, Shaoqing; Hou, Jianhui · Adv Mater · 2014

basic_science · Level V

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Abstract

The synergistic effect of fluorination on molecular energy level modulation is realized by introducing fluorine atoms onto both the donor and the acceptor moieties in a D-A polymer, and as a result, the polymer solar cell device based on the trifluorinated polymer, PBT-3F, shows a high efficiency of 8.6%, under illumination of AM 1.5G, 100 mW cm(-) (2) .

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