Single-molecule site-specific detection of protein phosphorylation with a nanopore.

Rosen, Christian B; Rodriguez-Larrea, David; Bayley, Hagan · Nat Biotechnol · 2014

basic_science · Level V

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Abstract

We demonstrate single-molecule, site-specific detection of protein phosphorylation with protein nanopore technology. A model protein, thioredoxin, was phosphorylated at two adjacent sites. Analysis of the ionic current amplitude and noise, as the protein unfolds and moves through an α-hemolysin pore, enables the distinction between unphosphorylated, monophosphorylated and diphosphorylated variants. Our results provide a step toward nanopore proteomics.

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