Low band-gap conjugated polymers with strong interchain aggregation and very high hole mobility towards highly efficient thick-film polymer solar cells.

Chen, Zhenhui; Cai, Ping; Chen, Junwu; Liu, Xuncheng; Zhang, Lianjie; Lan, Linfeng; Peng, Junbiao; Ma, Yuguang et al. · Adv Mater · 2014

basic_science · Level V

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Abstract

Absorption spectra of polymer FBT-Th4 (1,4) (M n = 46.4 Kg/mol, E g = 1.62 eV, and HOMO = -5.36 eV) indicate strong interchain aggregation ability. High hole mobilities up to 1.92 cm(2) (V s)(-1) are demonstrated in OFETs fabricated under mild conditions. Inverted solar cells with active layer thicknesses ranging from 100 to 440 nm display PCEs exceeding 6.5%, with the highest efficiency of 7.64% achieved with a 230 nm thick active layer.