Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: charge-transfer interaction and remarkable high ambipolar transport characteristics.
basic_science · Level V
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- Record sourced from PubMed, PMID 24664869.
- Also identified by DOI 10.1002/adma.201400056.
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Abstract
A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm(2) V(-1) s(-1) , respectively.