All-carbon vertical van der Waals heterostructures: non-destructive functionalization of graphene for electronic applications.

Woszczyna, Mirosław; Winter, Andreas; Grothe, Miriam; Willunat, Annika; Wundrack, Stefan; Stosch, Rainer; Weimann, Thomas; Ahlers, Franz et al. · Adv Mater · 2014

basic_science · Level V

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Abstract

Non-destructive chemical functionalization of graphene for applications in electronic devices (e.g., sensors or transducers) is achieved via assembly of carbon nanomembrane (CNM)/single-layer graphene (SLG) van der Waals heterostructures. The CNMs are 1 nm-thick, dielectric molecular sheets terminated with functional amino groups. The structure and performance of heterostructured field-effect transistors (FETs) are characterized by photoelectron/Raman spectroscopy and by electric transport measurements in vacuum, ambient conditions and water.