Highly sensitive gas sensor by the LaAlO3 /SrTiO3 heterostructure with Pd nanoparticle surface modulation.

Chan, Ngai Yui; Zhao, Meng; Huang, JianXing; Au, Kit; Wong, Man Hon; Yao, Hei Man; Lu, Wei; Chen, Yan et al. · Adv Mater · 2014

basic_science · Level V

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Abstract

The palladium nanoparticle (Pd NP)-decorated LaAlO3 /SrTiO3 (LAO/STO) heterostructure is for the first time used as a hydrogen-gas sensor with very high sensitivity and workability at room temperature. The outstanding gas-sensing properties are due to the Pd NPs' catalytic effect to different gases, resulting in charge coupling between the gas molecules and the two-dimensional electron gas (2DEG) through the Pd NPs by either a direct charge exchange or a change of the electron affinity. These results provide insight into the emerging properties at LAO/STO interfaces.