Carbon-encapsulated pyrite as stable and earth-abundant high energy cathode material for rechargeable lithium batteries.

Liu, Jun; Wen, Yuren; Wang, Yi; van Aken, Peter A; Maier, Joachim; Yu, Yan · Adv Mater · 2014

basic_science · Level V

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Abstract

Cathode materials consisting of porous pyrite nano-octahedra encapsulated by uniform carbon nanocages exhibit very high energy density, superior rate capability (reversible capabilities of 439, 340, and 256 mA h g(-1) at 1C, 2.5C, and 5C, respectively) and stable cycling performance (ca. 10% capacity loss after 50 cycles at 0.5C with a capacity retention of 495 mA h g(-1) ).